* denotes corresponding authors. † denotes equal contributions

50. J. Xu, K. Feng, W. Zhang, A. Venkatesh, I. Hung, Y. Liu, J. Liu, S. Li, G. Battiston, Z. Gan, S. Chen, Y.-M. Yiu, J. Zhong*, T.-K. Sham*, Y. Huang*. A Local Structure Analysis of Defects in UiO-66: Insights from Solid-State Nuclear Magnetic Resonance and X-ray Absorption Fine Structure.
J. Am. Chem. Soc. 2025, 147 (48), 44200-44215. DOI: 10.1021/jacs.5c13805

49. D. M. Halat,* H. Liu, K. Kim, G. C. B. Alexander, X. Wang, A. Venkatesh, A. R. Altenhof, H. E. Mason, S. H. Lapidus, J. S. Yoon, I. Hung, Z. Gan, J. Cabana, D. J. Siegel,* J. A. Reimer,* and B. Key*. Mg-Ion Conduction in Antiperovskite Solid Electrolytes Revealed by 25Mg Ultrahigh Field NMR and First-Principles Calculations.
J. Am. Chem. Soc. 2025, 147, 31, 27949-27961. DOI: 10.1021/jacs.5c07442

48. A. Dhakal, S. Jung, B. Bae, A. M. Arjun, S. Robinson, Y. Baek, W. T. Riffe, E. M. Tiernan, S. Gunaga, P. Verma, M. R. Phister, M. Stone, K. H. Stone, A. Morris, N. S. Swami, P. E. Hopkins, A. Venkatesh, K. Lee, and G. Giri*. Fabrication of Piezoelectric Polymer and Metal–Organic Framework Composite Thin Films Using Solution Shearing.
ACS Appl. Mater. Interfaces 2025, 17, 31, 44899-44909. DOI: 10.1021/acsami.5c07907

47. R. Wei, G. Casano, Y. Zhang, I. M. Gierbolini-Colón, Yu Rao, S. S. Gunaga, F. J. Scott, J. Zhou, S. Chatterjee, S. Kumari, H. Karoui, M. Huang, S. Th. Sigurdsson, G. De Paëpe, Y. Liu, F. Mentink-Vigier, A. Venkatesh, O. Ouari, L. Emsley*. Systematic Evaluation of Polarizing Agents for Dynamic Nuclear Polarization Enhanced NMR.
Angew. Chem. Int. Ed.  2025, e202505944. DOI: 10.1002/anie.202505944

46. W. Zhang, Y. Xu, A. Venkatesh, I. Hung, S. Li, Z. Gan, Y. Huang*. Pushing Limits of Ultra-Wideline Solid-State NMR Spectroscopy: NMR Signatures of 209Bi and 127I in Metal–Organic Frameworks at Ultra-high Magnetic Fields.
J. Am. Chem. Soc. 2025, 147, 13, 10823-10828. DOI: 10.1021/jacs.4c17499

45. S. Chatterjee, F. J. Scott, S. Th. Sigurdsson, A. Venkatesh, F. Mentink-Vigier*. Indirect Detection of the Protons in and Around Biradicals and their Mechanistic Role in MAS-DNP.
J. Phys. Chem. Lett. 2025, 16, 635-641. DOI: 10.1021/acs.jpclett.4c03254

44. A. Nelson, W. Papawassiliou, S. Paul, S. Hediger, I. Hung, Z. Gan, A. Venkatesh, W. T. T. Franks, M. E. E. Smith, D. Gajan, G. De Paëpe, C. Bonhomme, D. Laurencin*, C. Gervais*. Temperature-Induced Mobility in Octacalcium Phosphate Impacts Crystal Symmetry: Water Dynamics Studied by NMR Crystallography.
Faraday Discuss., 2025, 255, 451-482. DOI: 10.1039/D4FD00108G

43. R. Verma, C. Singhvi, A. Venkatesh*, V. Polshettiwar*. Defects Tune the Acidic Strength of Amorphous Aluminosilicates.
Nat. Commun. 2024, 15, 6899. DOI: 10.1038/s41467-024-51233-9

42. L. Corti, I. Hung, A. Venkatesh, Z. Gan, J. B. Claridge, M. J. Rosseinsky, F. Blanc*. Cation Distribution and Oxide Ion Diffusion Mechanism in the La3Ga5-xGe1+xO14+0.5x Langasite Structure.
J. Am. Chem. Soc. 2024, 146, 20, 14022-14035. DOI: 10.1021/jacs.4c02324

41. S. Chatterjee, A. Venkatesh, S. T. Sigurdsson*, F. Mentink-Vigier*. The Role of Protons in and around Strongly Coupled Nitroxide Biradicals for Cross-Effect Dynamic Nuclear Polarization.
J. Phys. Chem. Lett. 2024, 15, 2160-2168. DOI: 10.1021/acs.jpclett.3c03472.

40. L. Corti, I. Hung, A. Venkatesh, P. L. Gor’kov, Z. Gan, J. B. Claridge, M. J. Rosseinsky, F. Blanc*. Local Structure in Disordered Melilite Revealed by Ultrahigh Field 71Ga and 139La Solid-State Nuclear Magnetic Resonance. ChemPhysChem 2024, e202300934. DOI: 10.1002/cphc.202300934 

39. W. Zhang, B. Lucier, V. Martins, I. Hung, Y. Xu, Z. Gan, A. Venkatesh, T. W. Goh, W. Huang, A. J. Rossini, Y. Huang*. Local Order, Disorder, and Everything in Between: Using 91Zr Solid-State NMR Spectroscopy to Probe Zirconium-Based Metal-Organic Frameworks.
Phys. Chem. Chem. Phys. 2025, 27, 4704-4716. DOI: 10.1039/D4CP03704A

38. R. Wei, Y. Rao, A. Venkatesh, L. Emsley*. Solid Effect Dynamic Nuclear Polarization Enhancement of >500 at 9.4 T.
J. Phys. Chem. Lett. 2024, 15, 50, 12408-12415. DOI: 10.1021/acs.jpclett.4c03147

37. Y. Rao, P. Berruyer, A. Bertarello, A. Venkatesh, M. Mazzanti, L. Emsley*. An Efficient and Stable Polarizing Agent for In-Cell Magic-Angle Spinning Dynamic Nuclear Polarization NMR Spectroscopy.
J. Phys. Chem. Lett. 2024, 15, 46, 11601-11607. DOI: 10.1021/acs.jpclett.4c02709

36. L. Niccoli, G. Casano, G. Menzildjian, M. Yulikov, T. Robinson, S. -E. Akrial, Z. Wang, C. Reiter, D. Siri, A. Venkatesh, L. Emsley, D. Gajan, M. Lelli*, O. Ouari*, A. Lesage*. Efficient DNP at High Fields and Fast MAS with Antenna-Sensitized Dinitroxides.
Chem Sci. 2024, 15, 16582-16593. DOI: 10.1039/D4SC04473H

35. A. Venkatesh, G. Casano, R. Wei, Y. Rao, H. Lingua, H. Karoui, M. Yulikov, O. Ouari*, L. Emsley*. Rational Design of Dinitroxide Polarizing Agents for Dynamic Nuclear Polarization to Enhance Overall Sensitivity.
Angew. Chem. Int. Ed. 2024, 63, 9, e202317337. DOI: 10.1002/anie.202317337

34. M. A. Hope, Y. Zhang, A. Venkatesh, L. Emsley*. Dynamic Nuclear Polarisation of 1H in Gd-Doped In(OH)3.
J. Magn. Reson. 2023, 353, 107509. DOI: 10.1016/j.jmr.2023.107509

33. A. Venkatesh, G. Casano, Y. Rao, F. De Biasi, F. A. Perras, D. J. Kubicki, D. Siri, S. Abel, H. Karoui, M. Yulikov, O. Ouari*, L. Emsley*. Deuterated TEKPol Biradicals and the Spin-Diffusion Barrier in MAS DNP.
Angew. Chem. Int. Ed. 2023, 62, 31, e202304844. DOI: 10.1002/anie.202304844

32. A. Morales-Melgares, Z. Casar, P. Moutzouri, A. Venkatesh, M. Cordova, A. K. Mohamed, K. L. Scrivener*, P. Bowen*, L. Emsley*. Atomic-Level Structure of Zinc-Modified Cementitious Calcium Silicate Hydrate.
J. Am. Chem. Soc. 2022, 144, 50, 22915-22924. DOI: 10.1021/jacs.2c06749

31. Z. Wang, L. A. Völker, T. C. Robinson, N. Kaeffer, G. Menzildjian, R. Jabbour, A. Venkatesh, D. Gajan, A. J. Rossini*, C. Coperét*, A. Lesage*. Speciation and Structures in Pt Surface Sites Stabilized by N-Heterocyclic Carbene Ligands Revealed by Dynamic Nuclear Polarization Enhanced Indirectly Detected 195Pt NMR Spectroscopy Signatures and Fingerprint Analysis.
J. Am. Chem. Soc. 2022, 144, 47, 21530-21543. DOI: 10.1021/jacs.2c08300

30. Y. Rao, A. Venkatesh, P. Moutzouri, L. Emsley*. 1H Hyperpolarization of Solutions by Overhauser Dynamic Nuclear Polarization with 13C-1H Polarization Transfer.
J. Phys. Chem. Lett. 2022, 13, 33, 7749-7755. DOI: 10.1021/acs.jpclett.2c01956

29. A. Venkatesh, D. Gioffrè, B. Atterberry, L. Rochlitz, S. Carnahan, Z. Wang, G. Menzildjian, A. Lesage*, C. Coperét*, A. J. Rossini*. The Molecular and Electronic Structure of Isolated Platinum Sites Enabled by Expedient Measurement of 195Pt Chemical Shift Anisotropy.
J. Am. Chem. Soc. 2022, 144, 30, 13511-13525. DOI: 10.1021/jacs.2c02300

28. Y. Rao, C. T. Palumbo, A. Venkatesh, M. Keener, G. Stevanato, A. -S. Chauvin, G. Menzildjian, S. Kuzin, M. Yulikov, G. Jeschke, A. Lesage, M. Mazzanti*, L. Emsley*. Design Principles for the Development of Gd(III) Polarizing Agents for Magic Angle Spinning Dynamic Nuclear Polarization.
J. Phys. Chem. C 2022, 126, 27, 11310-11317. DOI: 10.1021/acs.jpcc.2c01721

27. A. N. Adeyemi, A. Venkatesh, C. Xiao, Z. Zhao. Y. Li, T. Cox, D. Jing, A. J. Rossini, F. E. Osterloh, J. V. Zaikina*. Synthesis of SrTiO3 and Al-doped SrTiO3 via the Deep Eutectic Solvent Route.
Mater. Adv. 2022, 3, 4736-4747. DOI: 10.1039/d2ma00404f

26. O. S. Lecina, M. A. Hope, A. Venkatesh, S. Björgvinsdóttir, K. Rossi, A. Loiudice, L. Emsley, R. Buonsanti*. Colloidal-ALD Grown Hybrid Shells Nucleate via a Ligand-Precursor Complex.
J. Am. Chem. Soc. 2022, 144, 9, 3998-4008. DOI: 10.1021/jacs.1c12538

25. B. A. Atterberry, S. L. Carnahan, Y. Chen, A. Venkatesh, A. J. Rossini*. Double Echo Symmetry-Based REDOR and RESPDOR Pulse Sequences for Proton Detected Measurements of Heteronuclear Dipolar Coupling Constants.
J. Magn. Reson. 2022, 336, 107147. DOI: 10.1016/j.jmr.2022.107147

24. D. B. Culver, R. W. Dorn, A. Venkatesh, J. Meeprasert, A. J. Rossini, E. A. Pidko, A. S. Lipton, G. R. Lief*, M. P. Conley*. Active Sites in a Heterogeneous Organometallic Catalyst for the Polymerization of Ethylene.
ACS Cent. Sci. 2021, 7, 7, 1225-1231. DOI: 10.1021/acscentsci.1c00466.

23. K. Boteju, A. Venkatesh, S. Wan, A. Ellern, A. J. Rossini, A. Sadow*. Ancillary Steric Effects on the Activation of SiH Bonds in Arylsilazido Rare Earth Compounds.
Organometallics 2021, 40, 11, 1654-1669. DOI: 10.1021/acs.organomet.1c00162

22. A. Venkatesh, F. A. Perras, A. J. Rossini*. Proton-Detected Solid-State NMR Spectroscopy of Spin-1/2 Nuclei with Large Chemical Shift Anisotropy.
J. Magn. Reson. 2021, 327, 106983. DOI: 10.1016/j.jmr.2021.106983

21. A. Venkatesh,† A. Lund,† L. Rochlitz, R. Jabbour, C. P. Gordon, G. Menzildjian, J. Viger-Gravel, P. Berruyer, D. Gajan, C. Copéret*, A. Lesage*, A. J. Rossini*. The Structure of Molecular and Surface Platinum Sites Determined by DNP-SENS and Fast MAS 195Pt Solid-State NMR Spectroscopy.
J. Am. Chem. Soc. 2020, 142, 44, 18936-18945. DOI: 10.1021/jacs.0c09101

20. A. Venkatesh, X. Luan, I. Hung, F. A. Perras, W. Huang, A. J. Rossini*. t1-Noise Eliminated Dipolar Heteronuclear Multiple Quantum Coherence Solid-State NMR Spectroscopy.
Phys. Chem. Chem. Phys. 2020, 22, 20815-20828. DOI: 10.1039/D0CP03511D

19. T. Egner, P. Naik, Y. An, A. Venkatesh, A. J. Rossini, I. I. Slowing*, V. Venditti*. ‘Surface Contrast’ NMR Reveals Non-Innocent Role of Support in Pd/CeO2 Catalyzed Phenol Hydrogenation.
ChemCatChem 2020, 12, 16, 4160-4166. DOI: 10.1002/cctc.202000608

18. A. V. Wijesekara,† A. Venkatesh,† B. J. Lampkin, B. VanVeller, J. W. Lubach*, K. Nagapudi*, I. Hung, P. L. Gork’kov, Z. Gan, A. J. Rossini*. Fast Acquisition of Proton Detected HETCOR Solid-State NMR Spectra of Quadrupolar Nuclei and Rapid Measurement of NH Bond Lengths by Frequency Selective HMQC and RESPDOR Pulse Sequences.
Chem. Eur. J 2020, 26, 35, 7881-7888. DOI: 10.1002/chem.202000390

17. R. W. Dorn, M. J. Ryan, T.-H. Kim, T. W. Goh, A. Venkatesh, P. Heintz, L. Zhou, W. Huang, A. J. Rossini*. Identifying the Molecular Edge Termination of Exfoliated Hexagonal Boron Nitride Nanosheets with Solid-State NMR Spectroscopy and Plane-Wave DFT Calculations.
Chem. Mat. 2020, 32, 7, 3109-3121. DOI: 10.1021/acs.chemmater.0c00104

16. A. Venkatesh, I. Hung, K. C. Boteju, A. D. Sadow, P. L. Gork’ov, Z. Gan, A. J. Rossini*. Suppressing 1H Spin Diffusion in Fast MAS Proton Detected Heteronuclear Correlation Solid-State NMR Experiments.
Solid State Nucl. Magn. Reson. 2020, 105, 101636. DOI: 10.1016/j.ssnmr.2019.101636

15. D. B. Culver, A. Venkatesh, W. Huynh. A. J. Rossini, M. P. Conley*. Al(ORF)3 (RF = C(CF3)3) Activated Silica: A Well-Defined Weakly Coordinating Surface Anion.
Chem. Sci. 2020, 11, 1510-1517. DOI:10.1039/c9sc05904k

14.  S. L. Carnahan, A. Venkatesh, F. A. Perras, J. F. Wishart, A. J. Rossini*. High-Field MAS Dynamic Nuclear Polarization Using Radicals Created by γ-Irradiation.
J. Phys. Chem. Lett. 2019, 10, 17, 4770-4776. DOI: 10.1021/acs.jpclett.9b01655

13.  B. S. Chang, B. Thomas, J. Chen, I. D. Tevis, P. Karanja, S. Çınar, A. Venkatesh, A. J. Rossini*, M. M. Thuo*. Ambient Synthesis of Nanomaterials by In Situ Heterogeneous Metal/Ligand Reactions.
Nanoscale 2019, 11, 29, 14060-14069. DOI: 10.1039/C9NR05448K

12.  A. Venkatesh, A. Wijesekara, L. O’Dell*, A. J. Rossini*. Comment on “Chirality-Induced Electron Spin Polarization and Enantiospecific Response in Solid-State Cross-Polarization Nuclear Magnetic Resonance”.
ACS Nano 2019, 13, 6, 6130-6132. DOI: 10.1021/acsnano.9b00221

11.  B. M. Schmidt, A. Pindwal, A. Venkatesh, A. Ellern, A. J. Rossini, A. D. Sadow*. Zwitterionic Trivalent (Alkyl)lanthanide Complexes in Ziegler-Type Butadiene Polymerization.
ACS Catal. 2019, 9, 2, 827-838. DOI: 10.1021/acscatal.8b04025

10.  M. A. White, K. J. Baulmer, Y. Chen, A. Venkatesh, A. M. Medina-Gonzalez, A. J. Rossini, J. V. Zaikina, E. M. Chan, J. Vela*. Expanding I-II-V Phase Space: Soft Synthesis of Polytypic Ternary and Binary Zinc Antimonides.
Chem. Mater. 2018, 30, 17, 6173-6182. DOI: 10.1021/acs.chemmater.8b02910

9. J. L. Stein, W. M. Holden, A. Venkatesh, M. E. Mundy, A. J. Rossini, G. T. Seidler*, B. M. Cossairt*. Probing Surface Defects of InP Quantum Dots Using Phosphorous Kα and Kβ X-ray Emission Spectroscopy.
Chem. Mater. 2018, 30, 18, 6377-6388. DOI: 10.1021/acs.chemmater.8b02590

8. A. Venkatesh, M. J. Ryan, A. Biswas, K. C. Boteju, A. D. Sadow, A. J. Rossini*. Enhancing the Sensitivity of Solid-State NMR Experiments with Very Low-Gyromagnetic Ratio Nuclei with Fast MAS and Proton Detection.\
J. Phys. Chem. A 2018, 122, 25, 5635-5643. DOI: 10.1021/acs.jpca.8b05107

7. K. C. Boteju, S. Wan, A. Venkatesh, A. Ellern, A. J. Rossini, A. D. Sadow*. Rare Earth Arylsilazido Compounds with Inequivalent Secondary Interactions.
Chem. Comm. 2018, 54, 7318-7321. DOI: 10.1039/C8CC03186J

6. Y. Nguyen, B. Lampkin, A. Venkatesh, A. Ellern, A. J. Rossini, B. VanVeller*. Open Resonance Assisted Hydrogen Bonds and Competing Quasiaromaticity.
J. Org. Chem. 2018, 83, 17, 9850-9857. DOI: 10.1021/acs.joc.8b01331

5. M. P. Hanrahan, A. Venkatesh, S. L. Carnahan, J. L. Calahan, J. Lubach, E. J. Munson*, A. J. Rossini*. Enhancing the Resolution of 1H and 13C Solid-State NMR Spectra by Reduction of Anisotropic Bulk Magnetic Susceptibility Broadening.
Phys. Chem. Chem. Phys. 2017, 19, 28153-28162. DOI: 10.1039/C7CP04223J

4. H. Nan, C. Zhang, A. Venkatesh, A. J. Rossini, J. L. Anderson*. Argentation gas chromatography revisited: Separation of light olefin/paraffin mixtures using silver-based ionic liquid stationary phases.
J. Chromatogr. A 2017, 1523, 316-320. DOI: 10.1016/j.chroma.2017.06.024

3. A. Venkatesh, M. P. Hanrahan, and A. J. Rossini*. Proton Detection of MAS Solid-State NMR Spectra of Half-Integer Quadrupolar Nuclei.
Solid State Nucl. Magn. Reson. 2017, 84, 171-181. DOI: 10.1016/j.ssnmr.2017.03.005

2. F. A. Perras, A. Venkatesh, M. P. Hanrahan, T. W. Goh, W. Huang, A. J. Rossini, and M. Pruski*. Indirect Detection of Infinite-Speed MAS Solid-State NMR Spectra.
J. Magn. Reson. 2017, 276, 95-102. DOI: 10.1016/j.jmr.2017.01.010

1. R. Kadu, V. Pillai, Amrit V., and V. K. Singh*. Synthesis and Spectral Characterization of Bimetallic Metallomacrocyclic Structures [MII2-μ2-bis-{(κ2S,S-S2CN(R)C6H4)2O}] (M = Ni/Zn/Cd): Density Functional Theory and Host-Guest Reactivity Studies.
RSC Adv. 2015, 5, 106688-106699. DOI: 10.1039/C5RA22175G